Environmental assessment of a BOF steel slag used in road construction : The ECLAIR research program

摘要

Steel production generates great amounts of by-products as steel slag. Unlike blast furnace slag, the use of Basic Oxygen Furnace slag (BOF slag) has been restrained due to insufficient volume stability and to the lack of environmental regulations. This study aimed at investigating the potential release and impact of pollutants, especially Cr and V that are present in rather high concentrations in slag, from a BOF slag used in a civil engineering structure (an industrial platform), using a multi-scale approach. The one-year follow up of the experimental platform showed that concentrations of Cr and V were generally low in seepage waters, and in leachates from leaching test. Micro-analyses carried out on slag allowed us to confirm the location of these metals in rather stable ferrous mineral phases, but V was also bound to more reactive silicates. No real toxicity effect of seepage waters has been revealed from eco-toxicological tests carried out with earthworms.